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In the crystal structure of the title solvated salt, C 16 H 19 N 2   + ·C 8 H 5 O 7 S − ·CH 3 OH, the anions and the methanol solvent mol­ecules are linked by O—H⋯O hydrogen bonds. The cations and anions are packed as alternate layers parallel to (11    ). The crystal structure is further stabilized by a π–π inter­action between the pyridinium and benzene rings of the cations, with a centroid–centroid distance of 3.5492 (4) Å.

4-{2-[4-(Dimethylamino)phenyl]ethenyl}-1-methylpyridinium 3,5-dicarboxybenzenesulfonate methanol monosolvate