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In the title co-crystal, C 20 H 40 N 4 ·2C 11 H 10 O, the macrocycle is generated by a crystallographic inversion centre. The N atoms show a pyramidal coordination, and the cyclo­hexane ring that is fused to the 14-membered C 10 N 4  ring exists in a chair conformation, whereas the methyl substituent occupies an axial site. The (naphthalen-1-yl)methanol mol­ecule forms an O—H⋯N hydrogen bond to a cyclam N atom. The mean-square-plane passing through the 14-membered ring is approximately coplanar with the naphthalene fused-ring [dihedral angle = 6.6 (1)°].

3,14-Dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.07,12]docosane–(naphthalen-1-yl)methanol (1/2)

3,14-Dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0^7,12]docosane–(naphthalen-1-yl)methanol (1/2)