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In the title compound, {[Fe(C 10 H 8 N 2 ) 2 (H 2 O) 2 ](C 12 H 7 N 2 O 4 S 2 ) 2 }  n  , synthesized by hydro­thermal reaction, the 4,4′-bipyridyl ligands (one with symmetry 2, one with symmetry) connect Fe 2+  cations, forming a cationic layer parallel to (001). The coordination of the Fe 2+  cation (site symmetry 2) is octahedral, with four N atoms from four 4,4′-bipyridyl ligands and O atoms from two  trans  water molecules. Adjacent layers are linked with each other by inter­molecular O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular structure. Parts of the nicotinic acid derivative are equally disordered over two sets of sites.

Poly[[diaquabis(μ2-4,4′-bipyridyl)iron(II)] bis{2-[(3-carboxypyridin-2-yl)disulfanyl]nicotinate}]

Poly[[diaquabis(μ₂-4,4′-bipyridyl)iron(II)] bis{2-[(3-carboxypyridin-2-yl)disulfanyl]nicotinate}]