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In the centrosymmetric tetra­nuclear title compound, [Cu 4 I 4 (C 10 H 8 N 2 S 2 ) 2 ], there are two different Cu I  atoms with tetra­hedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the second Cu I  atom is coordinated by a pyridine-N and three I atoms. Iodine bridges between the Cu I  atoms form a tetra­nuclear structure.

Bis(μ-di-2-pyridyl disulfide-κ3N,S:N′)di-μ3-iodido-di-μ2-iodido-tetracopper(I)

Bis(μ-di-2-pyridyl disulfide-κ³N,S:N′)di-μ₃-iodido-di-μ₂-iodido-tetracopper(I)