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In the title compound, [Co(C 4 H 7 N 2 O 2 ) 2 Cl(C 8 H 9 NO 2 )], which was prepared as a model complex of vitamin B 12 , the Co III  atom, which is linked to four N atoms of the pseudo-macrocyclic (dmgH) 2  ligand (dmgH is dimethyl­glyoximate) in the equatorial plane and one Cl −  anion and one N atom of ethyl nicotinate in apical positions, displays an approximately octa­hedral coordination. The Co atom is 0.0187 (8) Å out of the mean plane of the four equatorial N atoms. The structure has an O⋯H⋯O bridge, which is very common in cobaloxime derivatives, with O⋯H distances of 1.24 (2) and 1.25 (2) Å.

Chloridobis(dimethylglyoximato-κ2N,N′)(ethyl pyridine-3-carboxylate-κN)cobalt(III)

Chloridobis(dimethylglyoximato-κ²N,N′)(ethyl pyridine-3-carboxylate-κN)cobalt(III)