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The title complex, [Fe(C(36)H(36)N(4)O(4))Cl], shows a domed structure with a slightly distorted trapezoidpyramidal core, in which the perpendicular displacements of the Fe(III) atom from the mean pyrrole N(4) plane are 0.418 (3) and 0.465 (3) Å for the two crystallographically independent mol-ecules.

Chlorido(12,17-diethoxycarbonyl-11,18-dimethyl-2:3,6:7-dibutanocorrphycenato-κ4N)iron(III)

Chlorido(12,17-diethoxycarbonyl-11,18-dimethyl-2:3,6:7-dibutanocorrphycenato-κ⁴N)iron(III)