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In the title compound, [Ni(C 9 H 6 N 3 O 2 ) 2 (H 2 O) 4 ]·10H 2 O, the Ni II  ion lies on a twofold rotation axis and displays a slightly distorted octa­hedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules, two of which also lie on the twofold rotation axis. In the crystal, the complex mol­ecules and uncoordinated water mol­ecules are linked  via  inter­molecular O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. π–π inter­actions between the benzene rings provide additional stability of the crystal packing [centroid–centroid distance = 3.792 (2) Å].

Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN1]nickel(II) decahydrate

Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN¹]nickel(II) decahydrate