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In the title complex, {[CdI 2 (C 11 H 10 N 4 )]·C 3 H 7 NO}  n  , the Cd II  ion is four-coordinated by two N atoms from two 1-[(1 H -benzimidazol-1-yl)meth­yl]-1 H -imidazole (bmi) ligands and by two terminal I −  anions in a distorted tetra­hedral geometry. One of the two I −  anions is disordered over two sets of sites, with refined occupancies of 0.66 (5) and 0.34 (5). The Cd II  ions are bridged by bmi ligands, leading to the formation of a chain along [001]. Dimethyl­formamide solvent mol­ecules are located between these chains. Classical N—H⋯O hydrogen bonding between the bmi ligands and the solvent mol­ecules leads to a consolidation of the structure.

acta crystallographica. section e

catena-Poly[[(diiodidocadmium)-μ-{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κ2N:N′}]N,N-dimethylformamide monosolvate]