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In the title compound, [Mg(H 2 O) 6 ](C 8 H 6 N 5 O 2 )Cl·2H 2 O, the Mg II  ion is surrounded by six water mol­ecules, exhibiting a slightly distorted octa­hedral coordination. The pyridine and tetra­zole rings are nearly coplanar, forming a dihedral angle of 4.63 (3)°. The complex cations, zwitterionic organic anions, Cl −  anions and uncoordinated water mol­ecules are connected by O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds, leading to the formation of a three-dimensional network.

Hexaaquamagnesium 5-[1-(carboxylatomethyl)pyridin-1-ium-4-yl]tetrazol-2-ide chloride dihydrate