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In the title compound, (C 16 H 36 N)[Fe(C 12 H 8 N 3 O 2 )(CN) 3 ]·2H 2 O, the tetra- n -butyl­ammonium ion has a tetra­hedral configuration around the N atom, while the Fe III  atom of the tricyanido[ N -(2-pyridyl­carbon­yl)pyridine-2-carboximidato]iron(III) anion adopts a distorted octa­hedral geometry. O—H⋯O and O—H⋯N hydrogen bonds link the components in the crystal structure.

Tetra-n-butylammonium tricyanido[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]ferrate(III) dihydrate