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In the title compound, [Cu(C(7)H(7)N(2)O)Cl(C(7)H(8)N(2)O)]·3H(2)O, the metal ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethanone oxime ligands and by the chloride anion in a distorted square-pyramidal geometry. The distortion parameter is 0.192. The two organic ligands are linked by an intra-molecular O-H⋯O hydrogen bond. In the crystal, mol-ecules are linked by O-H⋯O and O-H⋯Cl hydrogen bonds. The title compound is the hydrated form of a previously reported structure [Wu &amp; Wu (2008 ▶). Acta Cryst. E64, m828]. There are only slight variations in the mol-ecular geometries of the two compounds.

acta crystallographica. section e

Chlorido[1-(pyridin-2-yl)ethanone oximato-κ2N,N′][1-(2-pyridyl)ethanone oxime-κ2N,N′]copper(II) trihydrate