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In the centrosymmetric title compound, [OsCl 2 (C 18 H 40 O 4 P 2 ) 2 ], the Os II  atom adopts a  trans -OsCl 2 P 4  geometry, arising from its coordination by two chelating diphosphane ligands and two chloride ions. One of the meth­oxy side chains of the ligand is disordered over two orientations in a 0.700 (6):0.300 (6) ratio.

Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ2P,P′}dichloridoosmium(II)

Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ²P,P′}dichloridoosmium(II)