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In the title compound, [Zn(C 24 H 21 N 7 )(H 2 O)](C 12 H 12 NO 3 S)(ClO 4 )·2.5H 2 O, the Zn II  ion is in a distorted trigonal–bipyramidal coordination geometry. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds connect the components into a two-dimensional network parallel to (001). In addition, there are weak C—H⋯O hydrogen bonds.

Aqua{tris[(1H-benzimidazol-2-yl-κN3)methyl]amine}zinc 5-(dimethylamino)naphthalene-1-sulfonate perchlorate 2.5-hydrate

Aqua{tris[(1H-benzimidazol-2-yl-κN³)methyl]amine}zinc 5-(dimethylamino)naphthalene-1-sulfonate perchlorate 2.5-hydrate