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In the title salt, [K 2 (C 6 H 4 O 8 S 2 )(H 2 O)]  n  , both K +  ions exhibit a seven-coordination with K—O bond lengths in the range 2.6600 (14) to 3.0522 (16) Å. One K +  ion is coordinated by seven O atoms from the sulfonate and phenolic hy­droxy groups of six 4,6-dihy­droxy­benzene-1,3-disulfonate ( L2− ) anions while the other K +  ion is coordinated by six O atoms from the sulfonate and phenolic hy­droxy groups of five  L2−  anions and one water O atom. The  L2−  anion exhibits chelating–bridging multidentate coordination to potassium, resulting in the formation of a cross-linked three-dimensional network.

Poly[aqua(μ11-4,6-dihydroxybenzene-1,3-disulfonato)dipotassium]

Poly[aqua(μ₁₁-4,6-dihydroxybenzene-1,3-disulfonato)dipotassium]