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In the title compound, [Zn(C 18 H 14 N 4 ) 2 (H 2 O) 4 ](NO 3 ) 2 ·1.49H 2 O, the Zn II  atom, lying on an inversion center, is coordinated by two N atoms from two  N , N ′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine ligands and four water mol­ecules in a distorted octa­hedral geometry. The nitrate anion is disordered over two sets of sites, with an occupancy ratio of 0.744 (4):0.256 (4). The uncoordinated water mol­ecule is also disordered with an occupancy factor of 0.744 (4). O—H⋯O and O—H⋯N hydrogen bonds link the complex cations, nitrate anions and uncoordinated water mol­ecules into a supra­molecular layer parallel to (102).

Tetraaquabis[N,N′-bis(pyridin-3-ylmethylidene)benzene-1,4-diamine]zinc dinitrate 1.49-hydrate