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In the title compound, C 12 H 14 O 2 S 3 , a chain transfer agent (CTA) used in polymerization, the dihedral angle between the aromatic ring and the CS 3  grouping is 84.20 (10)°. In the crystal, carb­oxy­lic acid inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate  R22 (8) loops.

3-({[(1-Phenylethyl)sulfanyl]methanethioyl}sulfanyl)propanoic acid