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In the title compound, [Fe(C 12 H 8 N 3 O 2 ) 2 ][Fe(C 12 H 8 N 3 O 2 )(CN) 3 ]·H 2 O, the Fe 3+  ions in the cation and anion each lie in a slightly distorted octa­hedral coordination environment. The solvent water mol­ecule is disordered over three positions with occupancies of 0.401 (7), 0.322 (7) and 0.277 (6). The water content was confirmed by thermogravimetric data.

acta crystallographica. section e

Bis[N-(pyridin-2-ylcarbonyl)pyridine-2-carboximidato-κ3N,N′,N′′]iron(III) tris(cyanido-κC)[N-(pyridin-2-ylcarbonyl)pyridine-2-carboximidato-κ3N,N′,N′′]ferrate(III) monohydrate