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In the title compound, [Fe 2 (C 4 H 2 N 2 S 2 )(C 3 H 9 P)(CO) 5 ], the Fe 2 S 2  core adopts a butterfly conformation. The PMe 3  ligand is coordinated in the basal position, roughly  cis  to the Fe—Fe bond. The Fe—Fe distance of 2.4970 (6) Å is relatively short compared to those ( ca  2.53 Å) found in another monosubstituted diiron compound. A rigid planar dithiol­ate bridge is featured, with an angle of 2.78 (1)° between the Fe—Fe bond and the normal to the pyrazine-2,3-dithiol­ate plane.

acta crystallographica. section e

Pentacarbonyl-1κ2C,2κ3C-(μ-pyrazine-2,3-dithiolato-1:2κ4S,S′:S,S′)(trimethylphosphane-1κP)diiron(I)(Fe—Fe)