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In the title compound, (C 10 H 10 N 3 O 2 S) 2 [CdCl 4 ], the Cd II  ion lies on a twofold axis and is coordinated by four chloride anions, with bond distances of 2.4787 (10) and 2.4410 (10) Å. A chain along the  c  axis is formed by C—H⋯N hydrogen-bonding inter­actions and a weak π–π inter­action is observed between the pyrimidine rings of two adjacent parallel chains [centroid–centroid distance = 3.722 (2) Å]. N—H⋯Cl, CN—H⋯Cl and N—H⋯O interactions also occur.

Bis{3-[2-(methylsulfonyl)pyrimidin-4-yl]pyridinium} tetrachloridocadmium