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In the title complex, [Co(C 4 H 6 N 2 ) 2 (H 2 O) 4 ](C 10 H 6 O 6 S 2 ), the cation and anion both reside on crystallographic inversion centers, such that the asymmetric unit comprises one half cation and one half anion. The central Co II  ion is coordinated by four water mol­ecules and two 2-methyl­imidazole ligands, resulting in a  trans -octa­hedral coordination geometry. The existence of strong N—H⋯O and O—H⋯O hydrogen-bonding inter­actions gives rise to a three-dimensional structure.

Tetraaquabis(2-methyl-1H-imidazole-κN3)cobalt(II) naphthalene-1,5-disulfonate

Tetraaquabis(2-methyl-1H-imidazole-κN³)cobalt(II) naphthalene-1,5-disulfonate