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In the title compound, [Ru(C 5 H 4 NO)(C 10 H 8 N 2 ) 2 ]PF 6 ·0.5C 6 H 6 , the Ru 2+  cation has a distorted octa­hedral RuN 5 O coordination environment. This complex is more distorted than the closely related ruthenium complex containing a pyridine-2-thiol­ate ligand [Santra  et al.  (1997  ▶ ).  J. Chem. Soc. Dalton Trans.  pp. 1387–1393]. The distortion is caused by the difference in size between the O and S atoms. The benzene solvent mol­ecule is situated on a twofold rotation axis.

Bis(2,2′-bipyridine)(pyridin-2-olato)ruthenium(II) hexafluoridophosphate benzene hemisolvate