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The asymmetric unit of title compound, [Co(C 3 H 10 NO 7 P 2 ) 2 (H 2 O) 2 ], contains one half-mol­ecule of the complex. The Co II  atom is located on an inversion centre and displays a distorted octa­hedral coordination geometry defined by four O atoms of two 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-bis­phospho­nato ligands in the equatorial plane and two water mol­ecules located in axial positions. The ligand mol­ecules, which exist in a zwitterionic state, form two six-membered chelate rings with chair conformations. In the crystal, mol­ecules are inter­linked by O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular structure.

Diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ2O,O′)cobalt(II)

Diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ²O,O′)cobalt(II)