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In the title compound, [Re(C 5 H 4 F 3 O 2 )(C 5 H 5 N)(CO) 3 ], the Re I  atom is six-coordinated owing to bonding by three carbonyl ligands arranged in a  fac  configuration, two O atoms from the bidentate 1,1,1-trifluoro­acetyl­acetonate ligand and an N atom from a pyridine ligand. In the crystal, the mol­ecules pack in layers, diagonally, in a head-to-tail fashion across the  ab  plane. These layers are stabilsed by inter­molecular C—H⋯O and C—H⋯F hydrogen bonds.

fac-Tricarbonyl(pyridine-κN)(1,1,1-trifluoroacetylacetonato-κ2O,O′)rhenium(I)

fac-Tricarbonyl(pyridine-κN)(1,1,1-trifluoroacetylacetonato-κ²O,O′)rhenium(I)