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In the asymmetric unit of title coordination polymer, {(C 16 H 36 N)[Zn 3 (C 9 H 3 O 6 ) 2 (OH)]·0.25H 2 O}  n  , there are three independent Zn 2+  cations, two benzene-1,3,5-tricarboxyl­ate ligands and a μ 3 -bridging hydroxide group, together with a tetra- n -butyl­ammonium counter-cation and a partially occupied water molecule of solvation (occupancy 0.25). Each Zn ion is coordinated by three carboxyl­ate O atoms and one O atom from the bridging hydroxide ion, displaying a slightly distorted tetra­hedral stereochemistry [overall Zn—O range = 1.875 (3)–1.987 (2) Å]. An intra­molecular hydrogen bond involving the hydroxide H atom and a carboxyl­ate O-atom acceptor is also present in the complex unit. The bridging benzene-1,3,5-tricarboxyl­ate anions generate a three-dimensional framework structure.

acta crystallographica. section e

Poly[tetra-n-butylammonium [(μ5-benzene-1,3,5-tricarboxylato)(μ4-benzene-1,3,5-tricarboxylato)-μ3-hydroxido-trizincate] 0.25-hydrate]