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The unique 3,4-ethyl­ene­dioxy­thio­phene (EDOT) unit of the title compound, C 24 H 22 N 2 O 8 S 3 ·C 3 H 6 O, is twisted by 1.9 (3)° relative to the central thio­phene ring. The three heterocyclic units are anti­periplanar. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds connect the heterocycles. π–π interactions occur between the central thiophene and the imine bond of the molecule [distance between the ring centroid of the ring and the azomethine bond = 3.413 (3) Å.

Diethyl 2,5-bis[(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)methylideneamino]thiophene-3,4-dicarboxylate acetone monosolvate