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The title complex, [Cu 2 I 2 (C 10 H 11 N 3 O 2 S) 2 (C 18 H 15 P) 2 ], is a centrosymmetric sulfur-bridged dimer of Cu I  with PPh 3  and iodine. The Cu I  atom shows a distorted tetra­hedral geometry, with bite angles ranging from 98.61 (2) to 120.16 (3)°. The intra­molecular Cu⋯Cu distance is 2.8228 (12) Å. The thio­semicarbazone ligand is coordinated only through the S atom. In the crystal, the complex mol­ecules are linked  via  inter­molecular N—H⋯O hydrogen bonds, resulting in a hydrogen-bonded chain along the  b  axis.

acta crystallographica. section e

Bis{μ-(E)-methyl 4-[(2-carbamothioylhydrazinylidene)methyl]benzoate-κ2S:S}bis[iodido(triphenylphosphane-κP)copper(I)]