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The title compound, [Li 4 O 4 (C 12 H 8 BO) 4 (C 4 H 10 O) 4 ], features a Li 4 O 4  cube. Each Li atom in the cube is additionally coordinated by a diethyl ether mol­ecule and each O atom in the cube carries a 9-oxa-10-boraanthracene residue. The crystal studied was a non-merohedral twin [twin law (-1 0 0 / 0 0 1 / 0 1 0); the contribution of the major twin component refined to 0.553 (3)] emulating apparent tetra­gonal symmetry, whereas the actual crystal system is just ortho­rhom­bic.

Tetrakis(μ3-9-oxa-10-boraanthracen-10-olato)tetrakis[(diethyl ether)lithium]

Tetrakis(μ₃-9-oxa-10-boraanthracen-10-olato)tetrakis[(diethyl ether)lithium]