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The two Co II  atoms in the title salt, [Co(H 2 O) 6 ][Co(C 4 H 4 O 4 S) 2 ]·4H 2 O, exist in an octa­hedral coordination environment. In the cation, the Co atom is surrounded by six water mol­ecules, and in the anion, it is  bis - O , S , O ′-chelated by the thio­acetate ligands. The cations, anions and uncoordinated water mol­ecules are linked by O—H⋯O hydrogen bonds into a three-dimensional network.

Hexaaquacobalt(II) bis(2,2′-sulfanediyldiacetato-κ3O,S,O′)cobaltate(II) tetrahydrate

Hexaaquacobalt(II) bis(2,2′-sulfanediyldiacetato-κ³O,S,O′)cobaltate(II) tetrahydrate