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In the title compound, [Fe(2)(C(7)H(13)NS(2))(C(26)H(24)P(2))(CO)(4)], the Fe(2)S(2) core exhibits a butterfly-like shape, with two S atoms bridging the Fe-Fe dumbbell. Each of the two Fe atoms exhibits a distorted octa-hedral environment. One Fe atom is additionally bonded to three carbonyl C atoms, whereas the other Fe atom is additionally bonded to one carbonyl C atom and two P atoms of the chelating dppe [dppe = 1,2-bis-(diphenyl-phosphan-yl)ethane] ligand. Non-classical intra-molecular C-H⋯S hydrogen-bonding inter-actions are present in the structure. The packing of adjacent mol-ecules along [100] is accomplished mainly through van der Waals forces.

acta crystallographica. section e

[1,2-Bis(diphenylphosphanyl)ethane-2κ2P,P′]tetracarbonyl-1κ3C,2κC-(μ-2-cyclopentyl-2-azapropane-1,3-dithiolato-1:2κ4S,S′:S,S′)diiron(II)(Fe—Fe)