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The title compound, [PtCl 2 (C 25 H 21 N 2 P)], is a Pt II  complex with an NPCl 2  coordination sphere in which the metal is coordinated to the imino N and phosphane P atoms of the ligand and to two chloride ions. The Pt II  atom is in a distorted square-planar environment and is bound to the ligand  via  the P and amine N atoms in a  cis  fashion, with the chlorine atoms located at the two remaining sites.

Dichlorido[2-diphenylphosphanyl-N-(pyridin-3-ylmethyl)benzylidenamine-κ2P,N]platinum(II)

Dichlorido[2-diphenylphosphanyl-N-(pyridin-3-ylmethyl)benzylidenamine-κ²P,N]platinum(II)