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In the title heterodinuclear complex, [CuNa(C 8 H 7 O 3 ) 2 (NO 3 )]  n  , the Cu II  ion is five-coordinated in a square-pyramidal arrangement by four atoms of two different ligand molecules in equatorial positions and one remote nitrate O atom in the apical position. The Na +  ion is eight-coordinated by four ligand O atoms and four nitrate O atoms. The ligand links the Cu II  and Na ions, forming a layered arrangement extending parallel to (001).

catena-Poly[[bis(μ-2-formyl-6-methoxyphenolato)copper(II)sodium]-μ-nitrato]