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The title compound, C 7 H 10 O 6 , was obtained from a regioselective enzyme-catalysed acyl­ation of  d -ribono-1,4-lactone. The five-membered ring of the acyl­ated sugar shows an envelope conformation. In the crystal, the mol­ecules are linked by inter­molecular O—H⋯O hydrogen-bonds, forming a one-dimensional polymeric structure parallel to [010]. In addition, packing analysis shows stacking along the  b  axis.

5-O-Acetyl-D-ribono-1,4-lactone