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In the title compound,  trans -[RhCl{P(C 10 H 7 ) 3 } 2 (CO)]·3C 3 H 6 O, where P(C 10 H 7 ) 3  is trinaphthyl­phosphine, the Rh—P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh—Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement.

trans-Carbonylchloridobis[tris(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone trisolvate