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The centrosymmetric mol­ecule of the title complex, [Cd 4 Cl 8 (C 3 H 4 N 2 ) 6 (C 3 H 7 NO) 2 ], contains four Cd II  atoms, six imidazole, two dimethyl­formamide and eight chloride ligands. The structure shows a novel chloride-bridged tetra­nuclear cadmium quasi-cubane cluster. The coordination geometry of all Cd II  atoms is distorted octa­hedral, with the two metal atoms in the asymmetric unit in different coordination environments. One of the Cd 2+  ions is coordinated by five Cl −  ions and by one N atom from an imidazole ligand, while the second is coordinated by three chloride ligands, two N atoms from two imidazole ligands and one O atom from a dimethyl­formamide mol­ecule. Inter­molecular N—H⋯Cl hydrogen bonds link the mol­ecules into a two-dimensional polymeric structure parallel to the  ab  plane.

acta crystallographica. section e

Di-μ3-chlorido-tetra-μ2-chlorido-dichloridobis(dimethylformamide-κO)hexakis(1H-imidazole-κN3)tetracadmium