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The asymmetric unit of the title compound, [MnI(C 8 H 6 N 4 ) 2 (H 2 O)]I·2H 2 O, contains a cationic Mn II  complex, an I −  anion and two solvent water mol­ecules. In the complex, the Mn II  ion is six-coordinated in a considerably distorted octa­hedral environment defined by four N atoms of the two chelating 2,2′-bipyrimidine (bpym) ligands, one I −  anion and one O atom of a water ligand. As a result of the different  trans  effects of the I and O atoms, the Mn—N bond  trans  to the I atom is slightly longer than the Mn—N bond  trans  to the O atom. The dihedral angle between the least-squares planes of the two bpym ligands [maximum deviation = 0.088 (4) Å] is 76.48 (6)°. In the crystal, the complex cation, the anion and the solvent water mol­ecules are linked by inter­molecular O—H⋯O, O—H⋯I and O—H⋯N hydrogen bonds.

cis-Aquabis(2,2′-bipyrimidine-κ2N1,N1′)iodidomanganese(II) iodide dihydrate

cis-Aquabis(2,2′-bipyrimidine-κ²N¹,N^1′)iodidomanganese(II) iodide dihydrate