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In the structure of title compound, [Rb(C 7 H 4 NO 5 )(H 2 O)]  n  , the centrosymmetric cyclic dimeric repeating unit comprises two irregular RbO 4  complex centres bridged by the carboxyl­ate groups of the 5-nitro­salicylate ligands. The coordination about each Rb atom is completed by a monodentate water mol­ecule and a phenolic O-atom donor which gives a bridging extension [Rb—O range = 3.116 (7)–3.135 (5) Å]. The polymeric structure is stabilized by inter­molecular water O—H⋯O carboxyl­ate  hydrogen bonds and weak inter-ring π–π inter­actions [minimum ring centroid separation = 3.620 (4) Å]. An intramolecular O—H⋯O hydrogen bond between phenol and carboxylate groups is also present.

Poly[aqua(μ3-2-hydroxy-5-nitrobenzoato-κ3O1:O1′:O2)rubidium]

Poly[aqua(μ₃-2-hydroxy-5-nitrobenzoato-κ³O¹:O^1′:O²)rubidium]