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In the title coordination polymer, [Cu 2 I 2 (C 14 H 14 N 4 )(C 18 H 15 P) 2 ]  n  , the Cu I  atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra­hedral arrangement. A crystallographic inversion centre generates a Cu 2 I 2  diamond with a Cu–Cu separation of 3.0120 (5) Å. The complete  N,N ′-(1-pyridin-4-yl-ethethyl­idene)-hydrazine mol­ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure.

catena-Poly[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]