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The two Al atoms in the title compound, [Al 2 (CH 3 ) 5 (C 23 H 20 NO)], are four-coordinated in a distorted tetra­hedral environment. The coordination of one Al atom includes three methyl-C atoms and the O atom from the ligand, whereas the second Al atom is surrounded by the O atom and one N atom from the ligand as well as by two methyl-C atoms. In the ligand, the dihedral angle between the two phenyl rings in the 9,10-dihydro­phenanthren unit is 20.64 (12)°.

[(E)-10-(2,6-Dimethylphenylimino)-9-methyl-9,10-dihydrophenanthren-9-olato]pentamethyldialuminum(III)