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In the title compound, C 6 H 18 N 22+ ·2C 9 H 3 Br 4 O 4− ·2CH 4 O, the carboxyl­ate and meth­oxy­carbonyl groups in one of the anions form dihedral angles of 71.9 (3) and 60.7 (3)°, respectively, with the aromatic ring while in the other anion these angles are 68.4 (3) and 56.8 (3)°, respectively. In the crystal, the constituent units are linked into a two-dimensional network parallel to the  ab  plane by N—H⋯O and O—H⋯O hydrogen bonds.

Hexane-1,6-diaminium bis[3,4,5,6-tetrabromo-2-(methoxycarbonyl)benzoate] methanol disolvate