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In the crystal structure of the title compound, C 8 H 7 N 3 O·H 2 O, adjacent organic mol­ecules are linked together into a tape along the  a  axis through N—H⋯N and N—H⋯O hydrogen bonds. On the other hand, water mol­ecules are linked together to form a chain along the  b  axis through O—H⋯O hydrogen bonds. The water chains and the organic mol­ecular tapes are further connected by inter­molecular O—H⋯O hydrogen bonds, forming a three-dimensional network. In addition, a π–π stacking inter­action between the 1,8-naphthyridine ring systems with an inter­planar separation of 3.246 (1) Å and a centroid–centroid distance of 3.825 (2) Å is observed.

7-Amino-1,8-naphthyridin-2(1H)-one monohydrate