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In the title complex, [Cu(C(4)H(5)NO(4))(C(6)H(6)N(2)O)(H(2)O)], conventionally abbreviated Cu(IDA)(4-OXPy)(H(2)O), where IDA is imino-diacetate and 4-OXPy is 4-(hy-droxy-imino-meth-yl)pyridine, the Cu(II) atom exhibits a distorted square-pyramidal coordination geometry, which is constructed from two O atoms and one N atom from a IDA ligand, one N atom from 4-OXPy ligand and one O atom from water. This mol-ecule looks like a space shuttle, the IDA ligand is its empennage (tail), and the 4-OXPy ligand is its airframe. The complexes are linked into two-dimensional supra-molecular layers parallel to (100) by three pairs of O-H⋯O hydrogen bonds. Two pairs of N-H⋯O hydrogen bonds further connect these supra-molecular layers, forming a three-dimensional supra-molecular network.

Aqua[4-(hydroxyiminomethyl)pyridine-κN1](iminodiacetato-κ3O,N,O′)copper(II)

Aqua[4-(hydroxyiminomethyl)pyridine-κN¹](iminodiacetato-κ³O,N,O′)copper(II)