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The title compound, C 12 H 18 N 4 O 2 SSi, was synthesized to be employed in a Julia–Kocieński olefination. In the mol­ecule, the dihedral angle between the phenyl ring and the tetra­zole ring is 41.50 (5)°. The significantly longer Si—C(methyl­ene) bond [1.8786 (13) Å] and the shortened adjacent C—C bond [1.5172 (18) Å], as well as the significant deviation of the corresponding Si—C—C angle [114.16 (9)°] from the ideal tetra­hedral angle, can be attributed to the β-effect of silicon. In the crystal, mol­ecules are held together by van der Waals inter­actions.

1-Phenyl-5-{[2-(trimethylsilyl)ethyl]sulfonyl}-1H-tetrazole