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The title compound, [Re(C(2)H(5)O)Cl(2)O(C(7)H(9)N)(2)], was crystallized from ethanol. The crystal structure of this complex contains a Re(V) atom in a slightly distorted octahedral coordination geometry with pairs of equivalent ligands in trans positions. Adjacent complex mol-ecules are linked by weak C-H⋯Cl hydrogen bonds. The crystal structure is additionally stabilized by π-π stacking inter-actions between the aromatic rings with centroid-centroid distances of 3.546 (4) Å.

trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)