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In the title complex, [Co(C 22 H 18 N 2 O 4 )(CN)(H 2 O)]·CH 3 CN, the Co III  ion is six-coordinated in a distorted octa­hedral environment defined by two N atoms and two O atoms from a salen ligand in the equatorial plane and one O atom from a water mol­ecule and one C atom from a cyanide group at the axial positions. O—H⋯O hydrogen bonds connect adjacent complex mol­ecules into dimers. C—H⋯N hydrogen bonds and π–π inter­actions between the benzene rings [centroid–centroid distances = 3.700 (2) and 3.845 (2) Å] are also present.

acta crystallographica. section e

Aqua(cyanido-κC){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ4O1,N,N′,O1′}cobalt(III) acetonitrile monosolvate