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In the heterodinuclear title complex, [GdZn(C 22 H 18 N 2 O 4 )(CH 3 COO) 3 ], the Zn II  ion is five-coordinated in a square-pyramidal environment defined by two O atoms and two N atoms from the ligand, forming the square plane, and one acetate O atom serving as the apex, while the Gd III  ion is nine-coordinated in an approximate mono-capped tetra­gonal–anti­prismatic environment defined by four O atoms from the ligand and five acetate O atoms.

μ-Acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc