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In the title cationic Cp * Fe(II) complex, [Fe(C 10 H 15 )(CH 3 CN)(C 14 H 16 NP)]PF 6 ·C 4 H 8 O, the metal ion is coordinated by the  η5 -Cp* ring as well as the P and N atoms of the chelating 2-(diphenyl­phosphino)ethyl­amine ligand and an additional acetonitrile mol­ecule in a piano-chair conformation. The PF 6−  anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7).

acta crystallographica. section e

(Acetonitrile-κN)[2-(diphenylphosphanyl)ethanamine-κ2N,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate