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In the title compound, {[Co 2 (C 16 H 6 O 8 )(C 12 H 8 N 2 )(H 2 O) 2 ]·H 2 O}  n  , one Co II  ion has a {CoN 2 O 4 } distorted octa­hedral environment defined by two N atoms of one 1,10-phenanthroline (phen) ligand, three O atoms of the carboxyl­ate groups of three biphenyl-3,3′,4,4′-tetra­carboxyl­ate (BPTC) ligands, one of which is bidentate, and one O atom from one coordinated water mol­ecule. The other Co II  atom is surrounded by six O atoms from four different BPTC ligands and one coordinated water mol­ecule. Each BPTC ligand forms eight coordination bonds with seven Co II  atoms, leading to a layer structure along the  ac  plane. Uncoordinated water mol­ecules occupy the space between the layers, and inter­act  via  inter­layer O—H⋯O hydrogen bonds along the  b  axis, generating a three-dimensional supra­molecular network.

Poly[[aqua(μ7-biphenyl-3,3′,4,4′-tetracarboxylato)(1,10-phenanthroline)dicobalt(II)] monohydrate]

Poly[[aqua(μ₇-biphenyl-3,3′,4,4′-tetracarboxylato)(1,10-phenanthroline)dicobalt(II)] monohydrate]