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In the title compound, [RhCl 3 (C 12 H 12 N 2 O)]·CH 2 Cl 2 , the Rh III  atom shows a slightly distorted octa­hedral geometry being coordinated by two N atoms and one O atom from the 2,2′-(oxydimethanedi­yl)dipyridine ligand and three Cl atoms. Two Cl atoms adopt a  trans  arrangement to the two pyridyl N atoms, while the third Cl atom and the O atoms occupy the axial site. The Rh—Cl bonds that are  trans  to the pyridyl N atoms are slightly longer than the Rh—Cl bond distance  trans  to the O atom.

acta crystallographica. section e

[Bis(pyridin-2-ylmethyl) ether]trichloridorhodium(III) dichloromethane monosolvate: unusual hydrolysis of the methylene bridge in (pyrazolylmethyl)pyridine