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In the trinuclear title compound, [Zn 3 Cl 6 (C 13 H 20 N 4 ) 2 ]·2H 2 O, each terminal Zn II  atom is coordinated by an N 3  donor set from the Schiff base ligands and two Cl atoms in a distorted square-pyramidal geometry. The central Zn II  atom is tetra­hedrally coordinated by two piperazine N atoms from two Schiff base ligands and two Cl atoms. The piperazine rings adopt chair conformations. In the crystal structure, adjacent complex mol­ecules are linked into a three-dimensional network  via  N—H⋯O, C—H⋯Cl and C—H⋯O hydrogen bonds. The structure includes two water mol­ecules, one of which is disordered over two positions with occupancies of 0.753 (15) and 0.247 (15).

Hexachloridobis{μ2-2-(piperazin-1-yl)-N-[1-(2-pyridyl)ethylidene]ethanamine}trizinc dihydrate

Hexachloridobis{μ₂-2-(piperazin-1-yl)-N-[1-(2-pyridyl)ethylidene]ethanamine}trizinc dihydrate