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The structure of the title manganese complex, [Mn(C 5 H 9 OS 2 ) 2 (C 5 H 5 N) 2 ] or [Mn(S 2 CO- n - Bu ) 2 (C 5 H 5 N) 2 ], consists of discrete monomeric entities with Mn 2+  ions located on centres of inversion. The metal atom is coordinated by a six-coordinate  trans -N 2 S 4  donor set with the pyridyl N atoms located in the apical positions. The observed slight deviations from octa­hedral geometry are caused by the bite angle of the bidentate κ 2 -S 2 CO- n - Bu  ligands [69.48 (1)°]. The O(CH 2 ) 3 (CH 3 ) chains of the  O - n -butyl dithio­carbonate units are disordered over two sets of sites with an occupancy ratio of 0.589 (2):0.411 (2).

Bis(O-n-butyl dithiocarbonato-κ2S,S′)bis(pyridine-κN)manganese(II)

Bis(O-n-butyl dithiocarbonato-κ²S,S′)bis(pyridine-κN)manganese(II)